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Title: Recycling process and proto-kimberlite melt metasomatism in the lithosphere-asthenosphere boundary beneath the Amazonian Craton recorded by garnet xenocrysts and mantle xenoliths from the Carolina kimberlite
Authors: Gervasoni, Fernanda
Jalowitzki, Tiago Luís Reis
Rocha, Marcelo Peres
Weska, Ricardo Kalikowski
Rodrigues, Eduardo Novais
Rodrigues, Rodrigo Antonio de Freitas
Yannick Bussweiler
Elisa Soares Rocha Barbosa
Jasper Berndt
Elton Luiz Dantas
Valmir da Silva Souza
Stephan Klemme
metadata.dc.identifier.orcid: https://orcid.org/0000-0002-9533-4008
https://orcid.org/0000-0002-8107-7055
metadata.dc.contributor.affiliation: Universidade Federal de Pelotas, Centro de Engenharias
Universidade Federal do Rio Grande do Sul, Programa de Pós-graduação em Geociências
Universidade de Brasília, Instituto de Geociências, Programa de Pós-graduação em Geologia
Universidade de Brasília, Instituto de Geociências, Programa de Pós-graduação em Geologia
Universidade Federal do Mato Grosso, Faculdade de Geociências
Universidade de Brasília, Instituto de Geociências, Programa de Pós-graduação em Geologia
Universidade de Brasília, Instituto de Geociências, Programa de Pós-graduação em Geologia
Universität zu Köln, Institut für Geologie und Mineralogie, Germany
Faculdade de Ciências e Tecnologia, Universidade Federal de Goiás
Universität Münster, Institut für Mineralogie, Münster, Germany
Universidade de Brasília, Instituto de Geociências, Programa de Pós-graduação em Geologia
Universidade de Brasília, Instituto de Geociências, Programa de Pós-graduação em Geologia
Universität Münster, Institut für Mineralogie, Münster, Germany
Assunto:: Xenólitos mantélicos
Craton amazônico
Metassomatismo
Issue Date: 2022
Publisher: Elsevier B. V.
Citation: GERVASONI, Fernanda et al. Recycling process and proto-kimberlite melt metasomatism in the lithosphere-asthenosphere boundary beneath the Amazonian Craton recorded by garnet xenocrysts and mantle xenoliths from the Carolina kimberlite. Geoscience Frontiers, [S. l.], v. 13, n. 5, 101429, set. 2022. DOI: https://doi.org/10.1016/j.gsf.2022.101429. Disponível em: https://www.sciencedirect.com/science/article/pii/S1674987122000822?via%3Dihub. Acesso em: 27 set. 2024.
Abstract: Here we present new data on the major and trace element compositions of silicate and oxide minerals from mantle xenoliths brought to the surface by the Carolina kimberlite, Pimenta Bueno Kimberlitic Field, which is located on the southwestern border of the Amazonian Craton. We also present Sr-Nd iso- topic data of garnet xenocrysts and whole-rocks from the Carolina kimberlite. Mantle xenoliths are mainly clinopyroxenites and garnetites. Some of the clinopyroxenites were classified as GPP–PP–PKP (garnet-phlogopite peridotite, phlogopite-peridotite, phlogopite-K-richterite peridotite) suites, and two clinopyroxenites (eclogites) and two garnetites are relicts of an ancient subducted slab. Temperature and pressure estimates yield 855–1102 °C and 3.6–7.0 GPa, respectively. Clinopyroxenes are enriched in light rare earth elements (LREE) (LaN/Yb N = 5–62; CeN/SmN = 1–3; where N = primitive mantle normal- ized values), they have high Ca/Al ratios (10–410), low to medium Ti/Eu ratios (742–2840), and low Zr/Hf ratios (13–26), which suggest they were formed by metasomatic reactions with CO 2-rich silicate melts. Phlogopite with high TiO 2 (>2.0 wt.%), Al 2O 3 (>12.0 wt.%), and FeOt (5.0–13.0 wt.%) resemble those found in the groundmass of kimberlites, lamproites and lamprophyres. Conversely, phlogopite with low TiO 2 (<1.0 wt.%) and lower Al2O 3 (<12.0 wt.%) are similar to those present in GPP-PP-PKP, and in MARID (mica-amphibole-rutile-ilmenite-diopside) and PIC (phlogopite-ilmenite-clinopyorxene) xenoliths. The GPP-PP-PKP suite of xenoliths, together with the clinopyroxene and phlogopite major and trace element signatures suggests that an intense proto-kimberlite melt metasomatism occurred in the deep cratonic lithosphere beneath the Amazonian Craton. The Sr-Nd isotopic ratios of pyrope xenocrysts (G3, G9 and G11) from the Carolina kimberlite are characterized by high 143 Nd/ 144 Nd (0.51287–0.51371) and eNd (+4.55 to +20.85) accompanied with enriched 87 Sr/86 Sr (0.70405–0.71098). These results suggest interac- tion with a proto-kimberlite melt compositionally similar with worldwide kimberlites. Based on Sr-Nd whole-rock compositions, the Carolina kimberlite has affinity with Group 1 kimberlites. The Sm-Nd iso- chron age calculated with selected eclogitic garnets yielded an age of 291.9 ± 5.4 Ma (2 r), which repre- sents the cooling age after the proto-kimberlite melt metasomatism. Therefore, we propose that the lithospheric mantle beneath the Amazonian Craton records the Paleozoic subduction with the attach- ment of an eclogitic slab into the cratonic mantle (garnetites and eclogites); with a later metasomatic event caused by proto-kimberlite melts shortly before the Carolina kimberlite erupted.
metadata.dc.description.unidade: Instituto de Geociências (IG)
metadata.dc.description.ppg: Programa de Pós-Graduação em Geologia
Licença:: This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).
DOI: https://doi.org/10.1016/j.gsf.2022.101429
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